1. A fully charged Lipo Battery is a 4.2V/cell, that is 12.6V for a 3S Lipo.
2. I suggest about 3.6V/cell per cell for first level protection, this is 10.8V for 3S LIPOs.
3. For second level i suggest to not go lower than 3.3V per cell because you might damage the Lipo pack, for a 3S this...